The precise measurement of NO2 was historically difficult in road tunnels, hence criteria and design analysis was based on converting from NOx concentrations via a set NO2:NOx ratio. The reliable direct measurement of NO2 is now possible, however design analysis is still dominated by emissions tables and formulas specified in terms of NOx. For converting from NOx to NO2 in a road tunnel environment in Australia, the ratio has typically been assumed to be tenpercent. This has generally been based on the recommendation in PIARC (2000) and on the average' value cited in PIARC (1995).Determining this ratio is important as changes in engine technology and in-tunnel pollution criteria along with improvements in CO and particulate emissions control, may mean that NO2 will become the driving factor for future ventilation requirements. Correct selection of this ratio can directly impact the ventilation capacity and system design.Recent research has indicated that choosing a constant ratio of tenpercent for all tunnels may not be appropriate. The in-tunnel ratio has been estimated to be as much as 20percent to 30percent and depends on the location in the tunnel, the type of ventilation system and the traffic/fleet characteristics. This paper discusses the effect of some of these parameters on the NO2:NOx ratio in road tunnels.The findings indicate that the tenpercent upper limit on the NO2:NOx ratio in PIARC (2000) may be a conservative value for design purposes for longitudinally ventilated road tunnels of typical length in Australia. A value of sevenpercent to eightpercent may be more appropriate in some circumstances. However, the value chosen will depend on the specific tunnel in question and the confidence in traffic conditions expected. Values above tenpercent may be encountered for short periods but usually when the NO2 levels are low.CITATION:O'Gorman, S and Gehrke, P, 2014._x000D_
NO2:NOx ratios in Australian road tunnels, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 95-102 (The Australasian Institute of Mining and Metallurgy: Melbourne).