Coal mining activity first began on the West Coast in 1864 and has since led to the exposure of large areas of coal and host rock to chemical weathering. These exposed abandoned workings have led to the formation of acid mine drainage, which flows into selected rivers and streams impacting on the natural environment. A previous study conducted for the West Coast Regional Council identified four catchments receiving mine drainage which had elevated arsenic concentrations. The aim of this research is to expand on this initial study by determining the spatial distribution and attenuation of the arsenic within the sediment and water column in each stream of concern. Cannel Creek is influenced from drainage from the Bellevue coal mine adit and exhibits a low pH of ~3, elevated sulfate concentrations and high arsenic and iron concentrations in the sediments. This pattern is repeated in the Rapid Stream and Soldiers Creek catchments, which are also affected by adit inflows from the Sullivan and Blackball coal mines respectively. Soldiers Creek also has significantly high arsenic in the waters, with an accompanying pH of ~5.5. Snowy River exhibits a similar trait with a pH also of ~5.5, but with very low sulfate concentrations. Arsenic concentrations in the waters are consistently around 30 ppb, with sediment concentrations up to 900 ppm. These sediment values might be partially attributable to the operation of the Snowy battery gold ore production facility, but the consistently high As concentrations in the water column and in the sediment upstream of the battery have an as yet unconfirmed source.