The influence of strongly chemisorbed solutes such as oxygen and sulphur on the rates of reactions at the gas-liquid iron interface is briefly reviewed. Deductions from recent studies of the rates of decarbur- ization of carbon-saturated liquid iron indicate ideal adsorption behaviour for sulphur over a wide temperature and composition range._x000D_
This is in fair accord with available infor- mation on surface tensions in the Fe-C-S system. Previously unpublished results for the kinetics of the 14C02-CO exchange reaction are in accord with ideal absorption of oxygen on liquid iron. The derived value for the ideal adsorption coefficient of oxygen at 1550C is in quantitative agreement with measurements of the depression of surface tension in the Fe-0 system. Consideration is given to the applicability of such results to the violently agitated systems of steelmaking.