At Tamano Smelter, part of the furnace settler is electrically heated by electrodes placed internally. This practice provides good control of the settler conditions. The authors have been investigating improvements in furnace operations, especially to decrease the copper content in the slag discarded from the settler. The important operational points on the control of magnetite in liquid matte and slag are discussed on the basis of the thermodynamic calculation method developed by Prof. S. Goto. The behaviour of magnetite in the practical furnace has been studied by using a torsion magnetometer and a solid electrolyte oxygen-sensing cell.