The present study was carried out to explore the possible separate recovery of iron and phosphorus (as gas) from BOF slag using graphite crucibles or graphite powders in the presence of a tin bath. The last is consider- ed to enhance the activity of phosphorus in iron reduced from slag or not to absorb the phosphorus vapour readily. When the slag was reduced in a graphite crucible in contact with a tin bath, the phosphorus reduced from the slag was carried away in CO explosively generated by the reduc- tion of iron oxide. When graphite powder was used as the reductant instead, 78% of the phosphorus was removed from slag, only 3% of which was absorb- ed into the tin bath. The rest left the system as gas. Gaseous dephosphorization depends on the area of contact between slag and reductant as cll n.u the amount of the latter. the reduction behaviour was directly observed, using an X ray transmission technique, to conlirm the reaction mechanism.