The oxidation of sphalerite particles of 60 to 100 mesh size was studied in a fluidized bed of low 02 concentration at 900C. Par- tial pressure of 02 in the fluidizing 02-N2 gas mixture was chosen between 0.0009 and 0.02 atm. In the region of p02 between 0.008 and 0.02 atm, the oxidation rate was lowered with the decrease of p02, and the unreacted-core model was applied. At lower pbelow 0.008 atm, the reaction rate was enhanced as compared with the calcu- lated values from the unreacted-core model._x000D_
From microscopic examination, it was found that ZnS was evaporated at the particle surface and the dissociated Zn vapor was oxidized in the gas phase. Initial reaction rate and the distance between the surface of inner sphaler- ite core and the oxide shell were studied based on the model of enhanced oxidation.