At the Copper Concentrator of Mount Isa Mines, the largest diluent of the copper concentrate is liberated fine pyrite. Laboratory flotation tests carried out as a function of grind and flotation Eh in combination with surface analysis by X-ray photoelectron spectroscopy (XPS) have identified the major mechanisms of iron sulphide flotation. It was found that a significant proportion of the iron sulphide minerals had surface coverages of graphitic carbon, sufficient to impart moderate hydrophobicity in the absence of collector. A smaller, but economically significant proportion of chalcopyrite was also affected by the graphitic carbon coating. Two methods were tested to reduce the impact of the natural floatability of the iron sulphides on concentrate grades. 1. Depression through the use of organic depressants. 2. Preflotation to remove the "naturally hydrophobic" iron sulphides (flotation independant of Eh ) prior to chalcopyrite flotation._x000D_
Preflotation was tested at the pilot plant scale. It was found that the amount of chalcopyrite reporting to the preflotation rougher concentrate could be minimised through flotation at a mildly reducing Eh by the use of nitrogen as the flotation gas to maintain the low Eh conditions resulting from grinding. The preflotation rougher concentrate was upgraded to an iron sulphide concentrate or a low grade copper concentrate.