In the Massif du Sud ophiolite complex platinum group elements occur predominantly as ultrafine-grained inclusions of rutheniridosmine, laurite and iridosmine. These form primary inclusions less than 5 to 10 um in diameter within chromite in podiform chromitite fringed by dunite, and emplaced subsequent to solidification of the host harzburgite. There is no specific association with trace inclusions of transition metal sulphides. The crystallization of then: Ir. Os and Ru minerals may have occurred concomitant with hromite, perhaps related to more reducing conditions produced by crystallization of the chromite. The Ir, Os. and Ru show pronounced fractionation from Pd, Pt and Rh expected to be also present in the mantle source rock. The dunite shows evidence of metasomatic origin from adjoining harzburgite, and the possibility of selective crystallization of the Ir sub-group elements suggests that Pd, Pt and Rh may have been transported elsewhere.