Studies of 13C/12C ratios of carbon dioxide in seam gases and in secondary calcites show that 1. In mines prone to carbon dioxide outbursting, the source of this gas is external to the coal. 2. Faults draining reservoirs of magmatic or primary carbon dioxide, rather than intrusives, are the most likely points of entry of carbon dioxide into mines. 3. The higher the concentration of carbon dioxide in seam gas and the wetter the mine, the lower the likelihood of secondary calcite occurring as a filling in cleats, fractures etc. 4. A -role played by carbon dioxide in promoting outbursting may be the conversion of calcite to soluble bicarbonate, the removal of this in mine water and the subsequent weakening of the resistance of the bulk coal to stress.