The presence of arsenic in solutions which result from the processing of many sulphide minerals leads to a need to understand its speciation in aqueous systems and the reactions of those various species. This paper deals in particular with the precipitation of arsenic from aqueous solution in the form of insoluble inorganic compounds in order to remove arsenic from various hydrometallurgical process streams. The solubility and stability of the precipitates is examined. It has been found that many of the arsenic compounds presently used are more soluble than previously accepted and unstable in disposal sites such as tailings ponds.