Conference Proceedings
The AusIMM Proceedings 1972
Conference Proceedings
The AusIMM Proceedings 1972
The Oxidation of Aqueous Ferrous Sulphate Solutions by Molecular Oxygen
The oxidation of ferrous sulphate to ferric sulphate with air and oxygen in a gas lift percolator was investigated with initial Fe2+ concentrations in the range 001 M to 10 M,temperatures in the range 20-80C, and pH in the range oto 2.The rate of formation of Fe3+ was found to be well described by the rate expressionEquation 1and a consistent mechanism is proposed.The presence of Cu2+ was found to cause an increased rate of oxidation, the effect being greater with Cu2+ concentrations increasing in the range 0001 M - 001 M in 02 M Fe2+. The effect of other solutes containing Ni, Zn, Mn, Co, Hg, Cl, Mo, NH4, As, Cr, or Na at a concentration of 0001 M in 02 M Fe2+ was negligible.
Contributor(s):
C T Mathews, R G Robins
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- Published: 1972
- PDF Size: 1.269 Mb.
- Unique ID: P_PROC1972_1328