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Conference Proceedings

The AusIMM Proceedings 1972

Conference Proceedings

The AusIMM Proceedings 1972

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The Oxidation of Aqueous Ferrous Sulphate Solutions by Molecular Oxygen

The oxidation of ferrous sulphate to ferric sulphate with air and oxygen in a gas lift percolator was investigated with initial Fe2+ concentrations in the range 001 M to 10 M,temperatures in the range 20-80C, and pH in the range oto 2.The rate of formation of Fe3+ was found to be well described by the rate expressionEquation 1and a consistent mechanism is proposed.The presence of Cu2+ was found to cause an increased rate of oxidation, the effect being greater with Cu2+ concentrations increasing in the range 0001 M - 001 M in 02 M Fe2+. The effect of other solutes containing Ni, Zn, Mn, Co, Hg, Cl, Mo, NH4, As, Cr, or Na at a concentration of 0001 M in 02 M Fe2+ was negligible.
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  • Published: 1972
  • PDF Size: 1.269 Mb.
  • Unique ID: P_PROC1972_1328

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