The application of biogeochemical methods in mineral exploration in semi-arid to arid environments in Western Australia has been investigated in an area near Norseman.The study involved a comparison of trace element characteristics of rock, soil and plants in the vicinity of the Pioneer BB prospect, where nickel-iron sulphide mineralization occurs in a "greenstone" sequence of ultrabasic, basic and sedimentary rocks.Analyses of unweathered and partly weathered rock from diamond drill cores show the ultrabasic rock to be highly variable with respect to Ni, Cu, Co, Zn and Mn.Samples of weathered bedrock and overlying soil were analysed for total trace element contents and for the trace elements associated with secondary iron and manganese oxides. Approximately 30 per cent of the total nickel content of the weathered basic rock is associated with secondary iron and manganese oxides, compared with approximately 15 per cent in the weathered ultrabasic rock.The soil has a sufficient residual content to provide a reliable indication of the chemistry of the underlying rock. Total trace element analyses of the -89 mesh fraction show strong anomalies for nickel and copper over the mineralized zone. Important amounts of nickel, cobalt and, to a lesser extent, copper are apparently associated with secondary iron and manganese oxides in the soil.Melaleuca sheathiana (tea tree) has been used to study the relationship between soil and plant chemistry. No strong relationship between plant and rock type was observed. Analyses were made of leaves, twigs, wood, bark and roots, and all plant organs were found to have anomalous nickel and copper contents near the mineralized zone. Leaves were found to give the best contrast in the anomalous area and to show fewer erratic values than other organs. It is concluded that the uptake of trace elements by tea tree is low in the semi-arid to arid environment of Western Australia, but that analyses of the plants do reflect the presence of mineralization.