Up to 80 per cent of the copper in a bornite ore can be quickly leached with percolating acidified ferric sulphate solutions. The upper limit for rapid copper extraction is set by the conversion of bornite to slowly dissolving chalcopyrite. The dissolution occurs in two stages: a rapid linear initial stage, followed by a slow, non-linear stage. The initial step is largely controlled by the rate of oxidant supply (Fe2(S04)3); temperature is not an important variable during the initial reaction. The second leaching stage is controlled by chemical and physical factors and is temperature dependent. The initial copper leaching rates are insensitive to both the concentration of the ferrous sulphate reaction product, and the sulphuric acid concentration.