The porphyry copper minerals of Melanesia occur within a host of narrow veinlets in predominantly quartz diorite stocks or as contact metasomatic masses in skarns adjacent to the intrusion. Some 90 per cent of the constituent minerals comprise pyrite or marcasite, chalcopyrite, and magnetite with the remainder mainly bornite and hematite with accessory rutile and chalcocite together with several trace minerals. Gold is found mainly as inclusions in chalcopyrite, and minor molybdenite occurs likewise.Of particular significance is the persistent occurrence of accessory rutile of hydrothermal origin intimately intergrown with chalcopyrite. The rutile occurs relatively late in the hydrothermal sequence and upon weathering of the deposit may be released on a cumulative basis possibly in sufficient amounts to constitute a particulate pathfinder mineral which may aid in prospecting.Rutile is present in all the Melanesian occurrences studied and is also prominent in several American deposits.The porphyry copper mineralogy is characterized by the presence of accessory hydrothermal rutile intergrown with chalcopyrite.