The present study 'of pure ZnS and NiS and ZnS (marmatite) by detailed electrokinetic methods has shown that by careful control of experimental parameters much new' information on sulphide-water interfaces can be obtained. Time-dependent processes of alteration of sulphide surfaces are foHowed by electrokinetic methods and indicate that the isoelectric point of the surface depends on elemental sulphur coverage, oxidation product coverage, and the conditions which promote or minimize such reaotions in the presence and absence of activator.