Bougainville copper concentrate was leached with a strain of Thiobacillus ferrooxidans (SPKI) in a 5 per cent CO2 nitrogen atmosphere.Copper solubilization was 100 per cent in presence of bacteria and only 30 per cent in a sterile acid control medium.Anaerobic copper solubilization rates were one quarter of those measured under aerobic conditions and did not generate acidity.