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Conference Proceedings

The AusIMM Proceedings 1989

Conference Proceedings

The AusIMM Proceedings 1989

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Reduction of Copper Sulphide with CO-cO2-He Gas Mixtures in the Presence of CaO

The kinetics of reduction of copper (cuprous) sulphide with CO-CO2-He gas mixtures, using an excess of CaO(s) as a sulphur-scavenging substance were investigated in the temperature range 855 - 950C by a thermogravimetric method. Several gas compositions were employed at each temperature. Potential carbon deposition was overcome by preheating the reducing gas mixture. The phase-composition and the morphology of partially reactedsamples were analysed by a SEMlEDAX unit. The reduction rates showed strong dependence on the bulk gas compositions (CO, CO2) and, in most cases, the rate declined with rising temperature. The rate-controlling step appears to be the diffusion of CO2 gaseous species through the micropores of the CaS(s) - product layer which builds up around the CaOcore.
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  • Reduction of Copper Sulphide with CO-cO2-He Gas Mixtures in the Presence of CaO
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  • Published: 1989
  • PDF Size: 4.756 Mb.
  • Unique ID: P_PROC1989_1736

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