Preliminary petrographic investigations of eight Upper Permian coal seams of the Muja sub-basin, Collie Coalfield, reveal that the coal is high in inertinite and relatively low in vitrinite and exinite contents. The exinite content of Collie coal is relatively high when compared to other Australian coal of similar age. In addition the mineral matter content of the coal is very much lower than comparable Permian coal of Eastern Australia. The higher exinite content could be attributed to the type of Glossopteris flora, and the lower mineral matter content to the environment of deposition postulated for the Collie Coal Measures.