With the development of new technology and materials of construction, chloride-based hydrometallurgical routes have gained accept- ance as a viable alternative to sulphate-based routes. A number of commercial and pilot plants built and operated over the last decade have provided invaluable experience and con- fidence in their use. Chloride hydrometal- lurgy, with or without pyrometallurgical pre- treatment, is particularly attractive for pro- cessing complex Cu/Pb/Zn/Ag concentrates, nickel mattes and chalcopyrite concentrates._x000D_
This review outlines recent developments, dis- cusses advantages, as well as indicating some of the problems still to be solved.