The Golden Valley Volcanic Centre has been recently interpreted as being a combination diatreme breccia pipe and rhyo-dacite flow dome complex of Permo-Carboniferous age that intrudes basement granitoids and sediments of Ordovician-Devonian age. Exceptionally good exposure at the Centre has enabled the relationships between different lithologies to be determined. This, along with petrological studies, has led to a detailed understanding of the geological environment in which the complex formed. Gold, silver and base metal mineralisation have been recently shown to be associated with the Marginal Breccia at the perimeter of the diatreme. Comparisons have been made between the geology and mineralisation in this system and several similar diatremes which also contain gold-base metal sulphide mineralisation.