The mineralised members of the Brockman Iron Formation mined at Mt Whaleback are overlain and underlain by shale horizons. To maximise resource recovery, waste movement within the life of mine plan will total approximately 3.3 billion tonnes. Approximately 15 per cent of waste materials contain zones with varying amounts of sulfides and carbon and are referred to as reactive shale'. Reactive shale has the potential to self-heat and can react with some explosives, resulting in spontaneous explosion. Sulfide rich zones also have the potential to generate acid rock drainage (ARD). Successful mining of reactive shale requires constant co-ordination between the geology, mine planning, mining and environment departments. Safe storage of reactive shale is the focus of ongoing research. Since the mid-1990s, a number of trials have been undertaken at Mt Whaleback in order to further the understanding of the physical and chemical properties of reactive shale. This paper summarises some of these trials, and discusses key learnings arising from interpretation of results. Ultimately, the learnings from this research will provide the guidelines for successful storage of reactive shale.